I've not seen any documentation on intergranular growth in steels yet, plenty on "fatigue", which often looks like some sort of embrittlement. Would enjoy seeing studies, though, if y'all could link some. ASME, SAE, ASTM, etc. or other countries' equivalents.
As for the degradation of aluminum alloys, it must be an environmental thing. The usual mechanism being "intergranular" corrosion. There's plenty of WWII bits at the shop which are brittle as can be. Other pieces of the same alloy are not badly degraded at all, but are from different recovery sites. As far as a 40 year life, there's 1930s DC3s still at work, and subject to FFA commercial inspections. Not to mention DC9s, B52s, etc.!Information
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